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CAS
# 75-50-3 TRIMETHYLAMINE |
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Blulux Laboratories Pvt. Ltd |
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HAZARD IDENTIFICATION
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Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES
Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO
Health Hazards Acute And Chronic: TOXIC BY INGESTION;BLOOD TOXIC.EYE CONTACT
MAY CAUSE BLINDNESS.SKIN CONTACT MAY CAUSE PERMANENT INJURY.PROD ABSORBED BY
SKIN.PERS W/ MAJOR SKIN CONT SHOULD BE UNDER MED OBSERVATION 24 HOURS (DELAYED
RXN POSS).INGESTION MAY CAUSE DEATH.CORR LIQUID.
Explanation of Carcinogenicity: N-NITROSAMINES,KNOWN TO BE CARCINOGENS,MAY BE
FORMED WHEN PROD CONTACTS NITROUS ACID,NITRITES,HIGH NO*X ATMOS (MFR).
Signs and Symptoms of Overexposure: EYES/SKIN:CONT:SEV
IRRIT,PAIN,BURNS,NECROSIS,PERM INJURY,BLINDNESS.EYES:VAP:LACRIM,CONJ,CORNEAL
EDEMA.SKIN:ABSORPTION:NAUS,HDCH,GEN DISCOMFORT.INGEST:MALAISE,DISCOMFORT,DEATH.INH:VAP:CHEM
PNEUM,PULM EDEMA,DELAYED SCARS OF AIRWAY/OTHER ORGAN S;RPTD/PRLNG EXPOS:CHRONIC
RESPIRATORY TRACT IRRITATION,BRONCHOPNEUMONIA.
Medical Conditions Aggravated by Overexposure: ASTHMA,SKIN DISORDERS &
ALLERGIES,CHRONIC RESPIRATORY DISEASE (BRONCHITIS,EMPHYSEMA),EYE DISEASE.
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FIRST AID
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EYES:FLUSH IMMED,GENTLY W/ LG VOL H*2O AT LEAST 15 MIN (HOLD LIDS APART).CALL
MD.SKIN:FLUSH 15 MIN W/ LG AMT H*2O.COVER W/ STERILE DRESSING.TRANSPORT FOR MED
CARE.DO NOT APPLY GREASE/OINTMENT.CTL SHOCK.INGEST:GIVE 3-4 GLASSES
MILK/H*2O.DO N OT INDUCE VOMIT.CALL MD.GET TO HOSPITAL IMMED.INH:MOVE TO FRESH
AIR.DFCLT BRTHG:GIVE MOUTH-TO-MOUTH RESP,O*2.DO NOT ALLOW ASPIR.KEEP AIRWAY
CLEAR.GET MED ATTN.
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FIRE FIGHTING MEASURES
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Flash Point Text: SEE SUPP DATA
Auto Ignition Temperature Text:
Lower Limits: 11.6% Upper Limits: 2%
Extinguishing Media: CARBON DIOXIDE,DRY CHEMICAL,ALCOHOL FOAM OR H*2O FOG
EXTING EQUIP CAN BE USED IN FIGHTING TRIMETHYLAMINE (CLASS B) FIRE.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA,FULL PROT EQUIP (FP
N),BUTYL RUB BOOTS,GLOVES.STOP GAS LEAK.COOL EXPOS CONTRS W/ H*2O
SPRAY.SAVE,DILUTE USED H*2O FOR PROPER DISP.
Unusal Fire/Explosion Hazard: FLAMM GAS/SOLN.GENERATES CLASS B FIRE IF EXPOS TO
HEAT,SPKS,OPEN FLAME.EXPLO MIX W/ AIR POSS IF FIRE IS EXTING BEFORE GAS IS SHUT
OFF.AUTO-IGNIT TEMP:374F,190C.
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RELEASE MEASURES
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Spill Release Procedures: EVAC PERS DOWNWIND.REMOVE IGNIT SOURCES.WEAR FULL
PROT EQUIP,RESP.SM:COVER W/ SODIUM BISULFATE.SPRAY W/ H*2O.CONTAIN CONTAM LIQ
FOR DISP.SPRAY LEAK W/ H*2O UNTIL PERS STOP LEAK.LG:REPORT SPILLS >1000 LBS
TO WATERS TO NATIONAL RESPONSE CENTE R.
Neutralizing Agent: SODIUM BISULFATE
Waste Disposal Methods: DISP MUST BE IAW FEDERAL,STATE & LOCAL REGS (FP
N).DO NOT DUMP TO SEWER/CLSD DRAINS PRESENTING FIRE/EXPLO HAZ.INCINERATION
ACCEPTABLE & PREF DISP METHOD.USE CAPABLE INDUST/MUNICIPAL WASTE TREATMENT
PLANT DEPENDING ON WASTE QUALITY,QTY,H*2O REGS.
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HANDLING AND STORAGE
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DO NOT WEAR CONT LENSES.CAUTION:AQ SOLN 5%/>5% FLAM.KEEP FROM HEAT,SPKS,OPEN
FLAME,DMG,ACID (SPATTER),HG.DO NOT BREATHE VAP/GET IN EYES,ON SKIN/CLTHG.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION
BELOW TLV (FP N/ORNL).
Protective Gloves: CUFFED BUTYL RUBBER
Eye Protection: CHEM WORKERS GOGGLES (FP N),FACESHLD.
Other Equipment: EMERGENCY SHOWERS AND EYE BATHS SHOULD BE READILY
ACCESSIBLE.WEAR BUTYL RUBBER APRON AND BOOTS.
Work Hygenic Practices: EMERGENCY SHOWERS AND EYE BATHS SHOULD BE READILY
ACCESSIBLE.WEAR BUTYL RUBBER APRON AND BOOTS.
Supplemental Safety & Health: VP:51 PSIG @ 126F,52C.% SOLN IN
H*2O:DENS:25%=0.94,40%=0.89;VP:25%=346 MMHG,40%=470
MMHG;FP:25%=43F,-6C;40%=39F,-4C.FL PT:8-18F,-13 TO -8C;25% SOLN IN H*2O
38-42F,3-6C.HAZ DECOMP PROD:NITRILES,CYANOGENS,CYANIC
ACID,ISOCYANATES,NITROSAMINES, AMIDES,CARBAMATES.LD50-LC50 MIX:DERMAL >2100
MG/KG;LC50 RAT INH 2000 PPM/L/HR.
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PHYSICAL AND CHEMICAL PROPERTIES
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Boiling Point:
39F,4C
Melting/Freezing Point:
-179F,-117C
Decomposition Temp:
N/K (FP N)
Vapor Pressure: 13 PSIG Vapor Density: 2.0,AIR=1
Specific Gravity: 0.66 (WATER=1)
PH: 10.71
Viscosity: N/P
Evaporation Rate & Reference: >1 (BUTYL ACETATE=1)
Solubility in Water: VERY SOLUBLE
Appearance and Odor: COLORLESS GAS (COLORLESS LIQUID BELOW 39F,4C) W/ STRONG
AMMONIA-LIKE,FISHY ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: N/K
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STABILITY AND REACTIVITY
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Stability Indicator: YES
Stability Conditions to Avoid: PRODUCT IS CHEMICALLY STABLE AND INSENSITIVE TO
LIGHT.
Materials to Avoid: OXIDIZING AGENTS (VIOLENT RXN,FIRE),ACIDS (RELEASE
HEAT);CU,AL,ZN (CORR);HG (EXPLO);NITROUS ACID,NITRITES,NO*X CONC.
Hazardous Decomposition Products: DECOMP:AMMONIA VAP;COMBUST:W/
O*2:CO/CO*2/NO*X GAS.NO*X+H*2O FORMS CORR NITRIC ACID;W/O O*2:CO,HYDROGEN
CYANIDE,(SUP DA)
Hazardous Polymerization Products: N/P
Conditions to Avoid Polymerization: N/K (FP N/ORNL)
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TOXICOLOGICAL
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N/P
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ECOLOGICAL
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N/P
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DISPOSAL
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DISP MUST BE IAW FEDERAL,STATE & LOCAL REGS (FP N).DO NOT DUMP TO
SEWER/CLSD DRAINS PRESENTING FIRE/EXPLO HAZ.INCINERATION ACCEPTABLE & PREF
DISP METHOD.USE CAPABLE INDUST/MUNICIPAL WASTE TREATMENT PLANT DEPENDING ON
WASTE QUALITY,QTY,H*2O REGS.
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TRANSPORTATION
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N/P
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REGULATORY
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SARA Title III: N/P
Federal Regulatory: N/P
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OTHER
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