CAS # 119 - 64 - 2 TETRALIN

Blulux Laboratories Pvt. Ltd
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1. General Information

Chemical Name:

1,2,3,4,-Tetrahydronaphthalene

Synonyms:

THN, Tetranap, Tetralin

Formula:

C10H12

Molecular Weight:

132.20

CAS #:

119-64-2

2. Hazardous Ingredients

1,2,3,4,-Tetranaphthalene:

85-99%

Naphthalene:

0-15%

Exposure Limits

1,2,3,4,-Tetranaphthalene:

None Established

Naphthalene:

10 ppm (50mg/m³) TLV-TWA
10 ppm (50mg/m³) PEL-TWA
15 ppm (75mg/m³) TLV-STEL
15 ppm (75mg/m³) PEL-STEL

3. Physical Data

Specific Gravity (H2O=1):

0.972 at 20/20°C

Boiling Point:

207.2°C

Melting Point:

N/A

Freezing Point:

-35.8°C

Vapor Pressure:

1 mmHg at 38°C

Vapor Density(air=1):

4.55

pH:

Unknown

Solubility in Water:

<0.01% weight at 60°C

Appearance and Odor:

Colorless to pale yellow liquid, moth-ball odor

4. Health Hazard Data

Oral LD50 (rats):

2860 mg/kg

Dermal LD50 (rabbits):

2000 mg/kg

Inhalation LC50
(guinea pig):

275 ppm

Skin Effects (rabbits):

Severe irritant

Eye Effects (rabbits):

Mild irritant

Carcinogenicity:

This product does not contain any chemicals listed as carcinogens by IARC, NTP, or OSHA.

Effects of Single Overexposure:

Ingestion- Initial symptoms include headache, confusion, sweating, nausea, vomiting, abdominal pain, and irritation of the bladder. Jaundice, hemolysis, and anemia may occur. Renal tubular blockage, acute renal shut down, transient liver damage, and production of grey-green urine may also occur. Aspiriatin may occur after swallowing this products and may result in pneumonitis.
Skin Absorbition-Harmful if absorbed through skin. May cause same symptoms as for swallowing.
Inhalation- May be harmful if inhaled and cause irritation to the respiratory tract. Headache, nausea, and vomiting. Inhaling from high concentrations may cause intravascular hemolysis.
Skin Irritation- Causes sever skin irritation.
Eye Contact- Causes eye irritation. Seen as tearing and redness. Vapors or sprays may be irritating to the eyes.

Effects of Repeated Overexposure:

Repeated may lead to contact dermatitis. May also cause more severe liver and kidney damage, dizziness, weakness, weight loss, nervousness, plus pain and numbness in the limbs. Repeated overexposure has caused cataracts in some animal studies.

Other Effects of Overexposure:

In sever cases of overexposure, may cause central nervous system depression or anemia.

Existing Medical Conditions Possibly Aggravated By Exposure:

Skin irritation may be aggravated in persons with existing skin lesions. Breathing of vapor or mists may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema or bronchitis. Individuals with a deficiency of glucose-6-phosphate dehydrogenase in erythrocytes are more susceptible to effects of hemolysis.

Emergency and First Aid Procedures:

Ingestion- If patient is conscious and alert, give 2-3 glasses of water to drink. Do not induce vomiting. Fet medical attention immediately. To prevent aspiration of swallowed product, lay patient on side with head lower than waist.
Skin- Immediately wash skin with plenty of soap and water, while removing contaminated clothing and shoes. Wash clothing separately before reuse.
Inhalation- Remove victim to fresh air. If not breathing, administer CPR or artificial respiration. If breathing is difficult, administer oxygen. Get medical attention.
Eyes- Hold eyelids open and flush with a steady, gentle stream of water for at least 15 mins. Get medical attention.

Notes To Physician:

No specific antidote is available. Treat symptomatically. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. This product is a liquid hydrocarbon. If large amounts (greater than 1ml/kg body weight) have been ingested, the stomach should be evacuated by gastric intubation with the aid of a cuffed endotracheal tube to prevent aspiration of the liquid hydrocarbon. After removal of stomach contents, wash stomach by instilling 30-50 grams of activated charcoal in 3-4 ounces of water through the stomach tube and again remove stomach contents. Avoid oily laxatives.

5. Fire and Explosion Hazard Data

Flash Point:

88°C (open cup)

Flammable Limits in Air
(% by volume):

Lower- 0.8
Upper- 5.0

Autoignition Temperature:

384°C

Extinguishing Media:

Use carbon dioxide or dry chemical for small fire. Use water spray or foam (alcohol, polymer, or ordinary) for large fire.

Special Firefighting Procedures:

1. Evacuate residents who are downwind of fire.
2. Prevent unauthorized entry to fire area.
3. Persons who may have been exposed to contaminated smoke should be examined by a physician and treated appropriately.
4. Dike area to prevent runoff and contamination of water sources.

Local Firemen Should:

1. Wear protective clothing and use self-contained breathing apparatus.
2. Be immediately relieved from duty, if exposed to contaminated smoke, and checked for symptoms of poisoning. These should not be mistaken for heat exhaustion or smoke inhalation. See section 4, Health Hazard Data for symptoms of poisoning, first aid procedures, and notes to the physician.

Unusual Hazards:

Combustion products may be hazardous. These may include carbon dioxide, carbon monoxide, and peroxides.

6. Reactivity Data

Stablility:

Stable

Conditions to Avoid:

This material oxidizes slowly in the presence of air to yeild peroxides, which may be dangerous at high concentrations and elevated temperatures. Keep away from heat, sparks, open flame, and other ignition sources.

Materials to Avoid:

Strong oxidizing agents (such as liquid oxygen, ozone, peroxides), concentrated mineral acids, halogens, and the presence of air at elevated temperatures and/or during long term storage.

Hazardous Decomposition Products:

Thermal decomposition may produce carbon monoxide, carbon dioxide, and peroxides.

Hazardous Polymerization:

Will not occur.

7. Spill or Leak Procedures:

Combustible Liquid:

Extinguish and do not turn on any ignition source until the area is determined t be free of any fire or explosion hazard.

Steps to be taken if material is released or spilled:

Dike large spills using absorbent or impervious materials such as sand or clay. Recover and contain as much free liquid as possible. Recover remaining spilled material as appropriate. Collect and contain contaminated absorbent and dike material for disposal. Absorb small spills on sand or vermiculite. Place contaminated material in appropriate container for disposal. If spilled on the ground, the affected area should be removed to a depth of 1-2 inches and placed in an appropriate container for disposal. Do not flush material to public sewers systems or any waterways. Wear appropriate protective clothing and equipment (see below) during cleanup activities. Ensure adequate decontamination to tools and equipment following cleanup.

Waste Disposal Method:

Dispose of in accordance with local, state, and federal regulations.

8. Special Protection Information

Protective Equipment Should Be Worn During:

-Manufacture or formulation of this product.
-Repair and maintenance of contaminated equipment.
-Clean up of leaks and spills.

Respiratory Protection:

Use NIOSH/MSHA approved respirator for organic vapors when handling spills or leaks, or when airborne concentrations exceed exposure limits.

Ventilation:

Local exhaust ventilation, when necessary.

Protective Gloves:

Chemical resistant gloves, e.g. pvc or butyl

Eye Protection:

Goggles, eye bath

Other Protective Equipment:

Protective clothing, saftey shower

9. Special Precautions

Precautions To Be Taken In Handling and Storing:

Do not swallow. Avoid breathing vapors or mists. Avoid getting in eyes, on skin, or on clothing. Keep away from heat, sparks, open flame, and other ignition sources. Store in a cool, dry place. Inert blanketing (nitrogen) may be used to minimize peroxide formation. Do not contaminate water, food, or feed by storage or disposal.

10. Regulatory Status

TSCA Inventory Status:

All components are listed on TSCA inventory.

RCRA Hazardous Waste:

U165, Naphthalene

Reportable Quantity (RQ), Under US EPA CERCLA:

1000 lbs. Naphthalene

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