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CAS
# 1314-80-3 PHOSPHORUS PENTASULFIDE for SYNTHESIS |
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Blulux Laboratories Pvt. Ltd |
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Section 1 - Chemical Product and
Company Identification |
MSDS
Name: Phosphorus pentasulfide
Synonyms: Diphosphorus pentasulfide; Sulfur phosphide; Thiophosphoric
anhydride.
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Section 2 - Composition,
Information on Ingredients |
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CAS# |
Chemical
Name |
Percent |
EINECS/ELINCS |
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1314-80-3 |
Phosphorus pentasulfide |
98-100 |
215-242-4 |
Hazard Symbols: XN F N
Risk Phrases: 11 20/22 29 50
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance:
gray to yellow-green crystalline. Stench. Causes severe eye and skin
irritation. Danger! Water-Reactive. May ignite or explode on contact
with moist air. Flammable solid. Harmful if inhaled or swallowed. Reacts with
water to form Hydrogen sulfide, Sulfur dioxide, and Phosphoric acid. Causes
respiratory tract irritation. May cause central nervous system effects.
Target Organs: Central nervous system, respiratory system,
eyes, skin.
Potential Health Effects
Eye: Contact may cause severe eye irritation and possible eye
damage.
Skin: Causes severe skin irritation.
Ingestion: Harmful if swallowed. May cause irritation of the
digestive tract.
Inhalation: May cause respiratory tract irritation. Vapors may
cause dizziness or suffocation. Inhalation of high concentrations may cause
pulmonary edema. Higher exposures may cause the loss of sense of smell
(anosmia). Inha lation overexposure may lead the CNS effect such as: headache,
dizzin ess, weakness, confusion, sweating, nausea, and vomiting. Higher leve ls
can cause seizures and death.
Chronic: Prolonged exposure to hydrogen sulfide may result in
pulmonary edema.
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Section 4 - First Aid Measures |
Eyes: Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and
alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Antidote: None reported.
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Section 5 - Fire Fighting
Measures |
General Information: As in any fire, wear a
self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. Vapors may form an explosive mixture
with air. Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Water Reactive.
Material will react with water and may release a flammable and/or toxic gas.
Containers may explode in the heat of a fire. Flammable solid. May ignite or
explode on contact with steam or moist air. Dangerous fire hazard in the form
of dust when exposed to heat or flame.
Extinguishing Media: Use dry sand or earth to smother fire.
Water may be ineffective. Do NOT use straight streams of water. DO NOT USE
WATER OR FOAM. For large fires, use dry sand, dry chemical, soda ash or lime or
withdraw from area and let fire burn. For small fires, use dry chemical, soda
ash, lime or dry sand.
Flash Point: Not available.
Auto ignition Temperature: 142 deg C ( 287.60 deg F)
Explosion Limits, Lower: N/A
Upper: N/A
NFPA Rating: (estimated) Health: 2; Flammability: 1;
Instability: 2; Special Hazard: -W-
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Section 6 - Accidental Release
Measures |
General Information: Use proper personal protective
equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Cover with sand, dry lime or soda ash and place in a closed
container for disposal. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation. Do not expose spill to water. A vapor suppressing foam may
be used to reduce vapors.
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Section 7 - Handling and Storage
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Handling: Wash thoroughly after handling. Remove contaminated clothing
and wash before reuse. Do not allow water to get into the container because of
violent reaction. Minimize dust generation and accumulation. Ground and bond
containers when transferring material. Use spark-proof tools and explosion
proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Avoid contact with heat, sparks and flame. Avoid
ingestion and inhalation. Do not allow contact with water. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep from contact with moist air and steam.
Storage: Keep away from sources of ignition. Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep away from
water. Flammables-area. Keep away from acids. Keep containers tightly closed.
Store away from alkalies. Separate from organic materials.
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Section 8 - Exposure Controls,
Personal Protection |
Engineering Controls: Use explosion-proof ventilation
equipment. Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
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Chemical
Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
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Phosphorus
pentasulfide |
1 mg/m3 TWA; 3 mg/m3 STEL |
1 mg/m3
TWA 250 mg/m3 IDLH |
1 mg/m3
TWA |
OSHA Vacated PELs: Phosphorus pentasulfide: 1 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection regulations in 29 CFR
1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to prevent skin
exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR
1910.134 or European Standard EN 149. Always use a NIOSH or European Standard
EN 149 approved respirator when necessary.
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Section 9 - Physical and
Chemical Properties |
Physical
State: Crystalline
Appearance: gray to yellow-green
Odor: stench
pH: Not available.
Vapor Pressure: 1 mmHg @ 300 C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 514 deg C @ 760.00mm Hg
Freezing/Melting Point:286.00 - 290.00 deg C
Decomposition Temperature:Not available.
Solubility: insoluable in cold water
Specific Gravity/Density:2.0300g/cm3
Molecular Formula:P4S10
Molecular Weight:444.48
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Section 10 - Stability and
Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures. Combines
vigorously or explosively with water. Contact with water or acids liberates
poisonous and flammable Hydrogen sulfide. Reaction with water also yields
Phosphoric acid, and Sulfur dioxide.
Conditions to Avoid: Ignition sources, dust generation, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, acids,
alcohols, alkalis, water, steam.
Hazardous Decomposition Products: Phosphine, oxides of phosphorus,
hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological
Information |
RTECS#:
CAS# 1314-80-3: TH4375000
LD50/LC50:
CAS# 1314-80-3:
Draize test, rabbit, eye: 20 mg/24H Moderate;
Draize test, rabbit, skin: 500 mg/24H Moderate;
Oral, rat: LD50 = 389 mg/kg;
Skin, rabbit: LD50 = 3160 mg/kg;<BR.
Carcinogenicity:
CAS# 1314-80-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Neurotoxicity: No information found.
Mutagenicity: No information found.
Other Studies: No data available.
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Section 12 - Ecological
Information |
Ecotoxicity: No data available.
No information available.
Environmental: Very toxic to aquatic organisms.
Physical: No information found.
Other: No information available.
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Section 13 - Disposal
Considerations |
Chemical
waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are
listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state
and local hazardous waste regulations to ensure complete and accurate
classification.
RCRA P-Series: None listed.
RCRA U-Series: CAS# 1314-80-3: waste number U189 (Reactive waste).
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Section 14 - Transport
Information |
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US DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
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Shipping
Name: |
PHOSPHORUS PENTASULFIDE |
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No
information available. |
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Hazard
Class: |
4.3 |
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UN
Number: |
UN1340 |
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Packing
Group: |
II |
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Section 15 - Regulatory
Information |
US
FEDERAL
TSCA
CAS# 1314-80-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
CAS# 1314-80-3: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1314-80-3: acute, chronic, flammable, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does
not contain any Class 1 Ozone depletors. This material does not contain any
Class 2 Ozone depletors.
Clean Water Act:
CAS# 1314-80-3 is listed as a Hazardous Substance under the CWA. None of the
chemicals in this product are listed as Priority Pollutants under the CWA. None
of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1314-80-3 can be found on the following state right to know lists:
California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are
listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN F N
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 29 Contact with water liberates toxic gas.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
WGK (Water Danger/Protection)
CAS# 1314-80-3: 2
Canada - DSL/NDSL
CAS# 1314-80-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B4, D2B, D1B, F.
Canadian Ingredient Disclosure List
CAS# 1314-80-3 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 1314-80-3: OEL-AUSTRALIA:TWA 1 mg/m3;STEL 3 mg/m3 OEL-BELGIUM:
TWA 1 mg/m3;STEL 3 mg/m3 OEL-DENMARK:TWA 1 mg/m3 OEL-FINLAND:STEL 1
mg/m3 OEL-FRANCE:TWA 1 mg/m3 OEL-GERMANY:TWA 1 mg/m3 OEL-THE NETHER
LANDS:TWA 1 mg/m3 OEL-THE PHILIPPINES:TWA 1 mg/m3 OEL-SWITZERLAND:TW
A 1 mg/m3;STEL 2 mg/m3 OEL-THAILAND:TWA 1 mg/m3 OEL-TURKEY:TWA 1 mg/
m3 OEL-UNITED KINGDOM:TWA 1 mg/m3;STEL 3 mg/m3 OEL IN BULGARIA, COLO
MBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VI
ETNAM check ACGI TLV
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Section 16 - Additional
Information |
Prepared
by: Blulux Laboratories Pvt. Ltd.
For questions contact: Blulux Laboratories
Pvt. Ltd.
79/66-B, I.H.I.Complex, Industrial Area, N.I.T. Faridabad,
Haryana-121001
TEL:
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The
statements contained herein are offered for informational purposes only and are
based upon technical data that Blulux Laboratories Pvt. Ltd. believes to be
accurate. It is intended for use only by persons having the necessary technical
skills and at their own discretion and risk. Since conditions and manner of use
are outside our control, we make NO WARRANTY, EXPRESS OR IMPLIED, OF
MERCHANTABILITY, FITNESS OR OTHERWISE.
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