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CAS
# METHYL ACETOACETATE |
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Blulux Laboratories Pvt. Ltd |
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SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - - NAME: METHYL ACETOACETATE SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - - CAS #:NONE MF: C5H8O3EC NO: 203-299-8 SYNONYMS ACETOACETIC METHYL ESTER * BUTANOIC ACID, 3-OXO-, METHYL ESTER (9CI) * METHYLACETOACETATE * METHYL ACETYLACETATE * METHYL ACETYLACETONATE * METHYLESTER KYSELINY ACETOCTOVE (CZECH) * METHYL 3-OXOBUTANOATE *METHYL 3-OXOBUTYRATE * 3-OXOBUTANOIC ACID METHYL ESTER * SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - - LABEL PRECAUTIONARY STATEMENTS IRRITANT IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. COMBUSTIBLE LIQUID. CAN CAUSE BLINDNESS. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE.WEAR SUITABLE PROTECTIVE CLOTHING. SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - - IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - - EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT. SPECIAL FIREFIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. UNUSUAL FIRE AND EXPLOSIONS HAZARDSCOMBUSTIBLE LIQUID. SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - - WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.SHUT OFF ALL SOURCES OF IGNITION. SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - - REFER TO SECTION 8. SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - - MECHANICAL EXHAUST REQUIRED. SAFETY SHOWER AND EYE BATH. WASH THOROUGHLY AFTER HANDLING. DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. NIOSH/MSHA-APPROVED RESPIRATOR. COMPATIBLE CHEMICAL-RESISTANT GLOVES. CHEMICAL SAFETY GOGGLES. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT AND OPEN FLAME.STORE IN A COOL DRY PLACE. SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - - APPEARANCE AND ODOR COLORLESS LIQUID PHYSICAL PROPERTIES BOILING POINT: 169 C TO 170 C MELTING POINT: -80 C FLASHPOINT 158 F EXPLOSION LIMITS IN AIR: UPPER 16% LOWER 3.1% AUTOIGNITION TEMPERATURE: 536 F VAPOR PRESSURE: 1.7MM 20 C SPECIFIC GRAVITY: 1.076VAPOR DENSITY: 4 SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - - STABILITY STABLE. INCOMPATIBILITIES STRONG OXIDIZING AGENTS HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE HAZARDOUS POLYMERIZATIONWILL NOT OCCUR. SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - - ACUTE EFFECTS CAUSES SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAUSES EYE IRRITATION. MAY BE HARMFUL IF INHALED. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. CAN CAUSE BLINDNESS. TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. RTECS #: AK5775000 ACETOACETIC ACID, METHYL ESTER IRRITATION DATA SKN-RBT 10 MG/24H OPEN JIHTAB 30,63,1948 SKN-RBT 500 MG/24H MLD FCTXAV 16,815,1978 EYE-RBT 2 MG SEV AJOPAA 29,1363,1946 TOXICITY DATA ORL-RAT LD50:3228 MG/KG JIHTAB 30,63,1948 ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FORCOMPLETE INFORMATION. SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - - DATA NOT YET AVAILABLE. SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - - THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - - CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - - EUROPEAN INFORMATION IRRITANT R 36 IRRITATING TO EYES. S 26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. REVIEWS, STANDARDS, AND REGULATIONS OEL=MAK NOHS 1974: HZD 84355; NIS 1; TNF 23; NOS 1; TNE 270 NOES 1983: HZD 84355; NIS 2; TNF 30; NOS 5; TNE 1872; TFE 336EPA TSCA SECTION 8(B) CHEMICAL INVENTORY SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - - _______________________________________________________________________________________ Prepared by: BLULUX LABORATORIES (P) LTD. For questions contact: Blulux Laboratories Pvt. Ltd.
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