CAS # 107 - 21 -1 ETHANEDIOL AR (Ethylene Glycol)

Blulux Laboratories Pvt. Ltd
79/66-B, I.H.I.Complex, H/W Chowk Industrial Area, N.I.T. Faridabad - 1, Haryana (India)
Tel. : + 91 129 4021360, 4190300  Fax : + 91 129 4190333
E-mail: bluluxlab@gmail.com  Website : www.blulux.com

Synonym

GLYCOL; 1,2-ETHANEDIOL

Material Uses

Analytical reagent.
 

Chemical Family

Polyalcohol

Section 2: Composition and Information on Ingredients

Component

CAS #

% by Weight

ETHYLENE GLYCOL

107-21-1

100

Section 3. Hazards Identification

Physical State and Appearance

Liquid.

Emergency Overview

WARNING!
MAY BE FATAL IF SWALLOWED.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA.
MAY BE HARMFUL IF INHALED OR ABSORBED THROUGH SKIN.
MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION.

Routes of Entry

Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Potential Acute Health Effects

Eyes

May be hazardous in case of eye contact (irritant).

Skin

May be hazardous in case of skin contact (permeator, irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Inhalation

May be hazardous in case of inhalation (lung irritant).

Ingestion

Extremely hazardous in case of ingestion. May be fatal if swallowed.

Potential Chronic Health Effects

Carcinogenic Effects

This material is not known to cause cancer in animals or humans.

Additional information See Toxicological Information (section 11)

Medical Conditions Aggravated by Overexposure:

Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4. First Aid Measures

Eye Contact

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Skin Contact

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.

Inhalation

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Ingestion

If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

Section 5. Fire Fighting Measures

Flammability of the Product

May be combustible at high temperature.

Auto-ignition Temperature

399.9°C (751.8°F)

Flash Points

Open cup: 110.9°C (231.6°F).

Flammable Limits

LOWER: 3.2% UPPER: 15.3%

Products of Combustion

These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances

Not available.

Explosion Hazards in Presence of Various Substances

Risks of explosion of the product in presence of static discharge: No.

Risks of explosion of the product in presence of mechanical impact: No.

Fire Fighting Media
and Instructions

SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Protective Clothing (Fire)

Be sure to use an approved/certified respirator or equivalent.

Special Remarks on Fire Hazards

Not available.

Special Remarks on Explosion Hazards

Not available.

Section 6. Accidental Release Measures

Small Spill and Leak

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Large Spill and Leak

Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Spill Kit Information

No specific spill kit required for this product.

Section 7. Handling and Storage

Handling

Avoid prolonged contact with eyes, skin, and clothing. Do not ingest. Avoid breathing vapors or spray mists. Keep container closed.

Storage

Keep container in a cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection

Engineering Controls

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection

Eyes

Splash goggles.

Body

Lab coat.

Respiratory

Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate.

Hands

Gloves.

Feet

Not applicable.

Personal Protection in Case of a Large Spill

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Product Name

Exposure Limits

ETHYLENE GLYCOL

AUVA (Austria, 1995). Skin
PEAK: 52 mg/m3 8 times per shift, Period: 5 minute(s).
PEAK: 20 ppm 8 times per shift, Period: 5 minute(s).
MAK: 26 mg/m3
MAK: 10 ppm
Belgium Minister of Labour (Belgium, 1998).
CEIL: 101 mg/m3
VCD: 101 mg/m3
BAUA (Germany, 1997). Skin
PEAK: 26 mg/m3
PEAK: 10 ppm
MAK: 26 mg/m3
MAK: 10 ppm
DK-Arbejdstylsinet (Denmark, 1996). Skin
GV: 26 mg/m3
GV: 10 ppm
Tyterveyslaitos (Finland, 1998).
STEL: 190 mg/m3
STEL: 75 ppm
TWA: 130 mg/m3
TWA: 50 ppm
INRS (France, 1996).
VLE: 125 mg/m3
VLE: 50 ppm
National Authority for Occupational Safety/Health (Ireland, 1999).
OEL: 10 mg/m3
Arbeidsinspectie (Netherlands, 1999).
TGG 8 uur: 26 mg/m3
TGG 8 uur: 10 ppm
N-Arbeidstylsinet (Norway, 1996).
AN: 25 ppm
AFS (Sweden, 1996). Skin
KTV: 50 mg/m3
KTV: 20 ppm
NGV: 25 mg/m3
NGV: 10 ppm
EH40-OES (United Kingdom (UK), 1997).
MEL: 10 mg/m3
ACGIH (United States, 1995).
CEIL: 100 mg/m3
OSHA Final Rule (United States, 1989).
CEIL: 125 mg/m3
CEIL: 50 ppm

Section 9. Physical and Chemical Properties

Odor

Odorless.

Color

Colorless.

Physical State and Appearance

Liquid.

Molecular Weight

62.08 g/mole

Molecular Formula

C2-H6-O2

pH

Not available.

Boiling/Condensation Point

197.05°C (386.7°F)

Melting/Freezing Point

-12.95°C (8.7°F)

Specific Gravity

1.1135 (Water = 1)

Vapor Pressure

Not available.

Vapor Density

2.14 (Air = 1)

Odor Threshold

Not available.

Evaporation Rate

0.01 compared to (n-BUTYL ACETATE=1)

LogKow

Not available.

Solubility

Soluble in water.

Section 10. Stability and Reactivity

Stability and Reactivity

The product is stable.

Conditions of Instability

Not available.

Incompatibility with Various Substances

Reactive with oxidizing agents, acids.

Rem/Incompatibility

Not available.

Hazardous Decomposition Products

Not available.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information

RTECS Number:

Ethylene Glycol

KW2975000

Toxicity

Acute oral toxicity (LD50): 4700 mg/kg [Rat].

Chronic Effects on Humans

Not available.

Acute Effects on Humans

May be hazardous in case of eye contact (irritant). May be hazardous in case of skin contact (permeator, irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. May be hazardous in case of inhalation (lung irritant). Extremely hazardous in case of ingestion. May be fatal if swallowed.

Synergetic Products (Toxicologically)

Not available.

Irritancy

Draize Test (Rabbit):
Eyes: 500mg/24h. Reaction: Mild.

Sensitization

Not available.

Carcinogenic Effects

This material is not known to cause cancer in animals or humans.

Toxicity to Reproductive System

Tests on laboratory animals for reproductive effects are cited in Registry of Toxic Effects on Chemical Substances (RTECS).

Teratogenic Effects

Not available.

Mutagenic Effects

Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical Substances (RTECS).

Section 12. Ecological Information

Ecotoxicity

Not available.

BOD5 and COD

Not available.

Toxicity of the Products of Biodegradation

The products of degradation are less toxic than the product itself.

Section 13. Disposal Considerations

EPA Waste Number

Not available.

Treatment

Material does not have an EPA Waste Number and is not a listed waste, however consultation with a permitted waste disposal site (TSD) should be accomplished. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.

Section 14. Transport Information

DOT Classification

Proper Shipping Name: CHEMICALS, N.O.S.
RQ: 5000 lbs. (2268 kg)

TDG Classification

Not available.

IMO/IMDG Classification

Not available.

ICAO/IATA Classification

Proper Shipping Name: CHEMICALS, N.O.S.
RQ: 5000

Section 15. Regulatory Information

U.S. Federal Regulations

TSCA 8(b) inventory: ETHYLENE GLYCOL

SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: ETHYLENE GLYCOL
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: ETHYLENE GLYCOL: Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard

SARA 313 toxic chemical notification and release reporting: ETHYLENE GLYCOL

Clean Water Act (CWA) 307: No products were found.

Clean Water Act (CWA) 311: No products were found.

Clean air act (CAA) 112 accidental release prevention: No products were found.

Clean air act (CAA) 112 regulated flammable substances: No products were found.

Clean air act (CAA) 112 regulated toxic substances: No products were found.

WHMIS (Canada)

Class D-2B: Material causing other toxic effects (TOXIC).
 

CEPA DSL: ETHYLENE GLYCOL

This product has been classifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all required information.

International Regulations

EINECS

ETHYLENE GLYCOL 203-473-3

DSCL (EEC)

R22- Harmful if swallowed.

International Lists

Australia (NICNAS): ETHYLENE GLYCOL

Japan (MITI): ETHYLENE GLYCOL

Korea (TCCL): ETHYLENE GLYCOL

Philippines (RA6969): ETHYLENE GLYCOL

China: No products were found.

State Regulations

Pennsylvania RTK: ETHYLENE GLYCOL: (environmental hazard, generic environmental hazard)
Massachusetts RTK: ETHYLENE GLYCOL
New Jersey: ETHYLENE GLYCOL

California prop. 65: No products were found.

Mfgs. & Exporters: Laboratory Reagents, Fine Chemicals, Analytical Reagents & Dehydrated Culture Media